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2 年
Atherton-Todd反应
亚磷酸二酯在温和的碱性条件下与四氯化碳的作用,把P-H键转换成P-Cl键,制备得到氯磷酸二酯的反应称为Atherton-Todd反应。由于 氯磷酸二酯活性太高很难分离,一般情况下会接着和醇或胺反应合成磷酸酯或磷酰胺。 该反应是1945年F. R. Atherton, H. T. Openshawand ...
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